Bis(4′-chloro-2,2′:6′,2′′-terpyridine-κ3 N,N′,N′′)ruthenium(II) dichloride dihydrate
نویسندگان
چکیده
In the cation of the title compound, [Ru(C(15)H(10)ClN(3))(2)]Cl(2)·2H(2)O, the metal atom exhibits a distorted octa-hedral coordination geometry provided by the N atoms of two tridentate terpyridine ligands. The ligands are approximately planar [maximum deviation = 0.156 (5) Å] and form a dihedral angle of 87.0 (3)°. In the crystal, the cations, anions and water mol-ecules are linked into a three-dimensional network by C-H⋯Cl, C-H⋯O and O-H⋯Cl hydrogen bonds.
منابع مشابه
Bis(4′-chloro-2,2′:6′,2′′-terpyridine-κ3 N,N′,N′′)iron(II) dinitrate dihydrate
The title complex, [Fe(C(15)H(10)ClN(3))(2)](NO(3))(2)·2H(2)O, has a six-coordinate iron(II) center balanced by two nitrate anions. The Fe atom lies on a twofold rotation axis. The complex exhibits an octa-hedral coordination configuration, where the dihedral angle between the two planar tridentate ligands is 92.4 (1)°. The crystal structure involves O-H⋯O hydrogen bonds.
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عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012